Your boiler flow temperature is the temperature your boiler heats your water to before it gets sent to your radiators.
As it flows through the radiators, the water cools before it returns to the boiler. The temperature of the water at this point is the return temperature.
Reducing the flow temperature also lowers the return temperature. Boilers are more efficient when the return temperature is low, and this can save you both energy and money. For more information, see our guide on boiler controls.